| Disc 1 |
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| Music by Dennis McCarthy |
| * Music by Dennis McCarthy & Kevin Kiner |
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| 01 Where My Heart Will Take Me (Main Title, Season One) (1:25) |
| Written by Diane Warren |
| Performed by Russell Watson |
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| Shockwave, Part I #026 |
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| 02 Disaster (0:56) |
| 03 Eulogy (1:43) |
| 04 Daniels Arrives (3:02) |
| 05 Hide and Seek (3:34) |
| 06 No Return (3:41) |
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| Recorded May 15, 2002 |
| Original Airdate: May 22, 2002 |
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| Shockwave, Part II #028 |
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| 07 A Refresher (1:43) |
| 08 Playing Possum (2:16) |
| 09 The Captain (2:25) |
| 10 Onward (0:23) |
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| Recorded September 10, 2002 |
| Original Airdate: September 18, 2002 |
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| The Expanse #052 |
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| 11 Florida Attack (0:47) |
| 12 On the Team (2:12) |
| 13 Now There Is One / Loop-de-Loop (5:02) |
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| Recorded May 14, 2003 |
| Original Airdate: May 21, 2003 |
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| Impulse #057 |
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| 14 Blocked Exit (2:57) |
| 15 Paranoia (2:02) |
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| Recorded October 1, 2003 |
| Original Airdate: October 8, 2003 |
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| Twilight #060 |
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| 16 Armageddon (1:40) |
| 17 Rip Van Winkle / Angst (2:05) |
| 18 Showdown / Back to the Past (6:59) |
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| Recorded October 1, 2003 |
| Original Airdate: October 8, 2003 |
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| Carpenter Street #063 |
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| 19 Street Walkin' (3:05) |
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| Recorded November 19, 2003 |
| Original Airdate: November 26, 2003 |
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| Kir'Shara* #085 |
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| 20 Kir'Shara Activated (3:29) |
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| Recorded November 23, 2004 |
| Original Airdate: December 3, 2004 |
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| Countdown* #075 |
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| 21 Re–Cap Enterprise 075 (1:32) |
| 22 Ready to Fire (3:27) |
| 23 Countdown Begins (1:10) |
| 24 Hays Departs (1:34) |
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| Recorded May 3, 2004 |
| Original Airdate: May 19, 2004 |
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| Storm Front, Part II* #078 |
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| 25 Recap–Enterprise 078 (1:10) |
| 26 Fight to the Death (3:06) |
| 27 Stukas Coming / The Vortex (3:11) |
| 28 Timeline Restored (1:19) |
| 29 Home at Last (1:39) |
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| Recorded September 23, 2004 |
| Original Airdate: October 15, 2004 |
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| 30 Where My Heart Will Take Me (End Credits Instrumental) (1:03) |
| (Diane Warren) |
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| Disc 2 |
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| Music by Jay Chattaway |
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| 01 Where My Heart Will Take Me (Main Title, Season Three) (1:22) |
| Written by Diane Warren |
| Performed by Russell Watson |
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| Civilization #009 |
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| 02 Old City (2:34) |
| 03 Entering the Reactor / Reactor Surprise (3:13) |
| 04 Memorable (0:29) |
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| Recorded November 6, 2001 |
| Original Airdate: November 14, 2001 |
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| The Catwalk #038 |
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| 05 Taking Back Enterprise / Capitan a Capitan / Core Is Down (7:43) |
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| Recorded December 11, 2002 |
| Original Airdate: December 18, 2002 |
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| North Star #061 |
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| 06 Hangin' Offense (1:01) |
| 07 Gunfight / Final Fight (4:17) |
| 08 New School (0:59) |
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| Recorded November 5, 2003 |
| Original Airdate: November 11, 2003 |
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| Zero Hour #076 |
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| 09 Sphere Builder On Board / Andorian Offensive / Sphere / Final Showdown (12:03) |
| 10 My Captain (2:29) |
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| Recorded May 13, 2004 |
| Original Airdate: May 26, 2004 |
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| Storm Front, Part I #077 |
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| 11 Daniels' Goodbye (2:50) |
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| Recorded September 16, 2004 |
| Original Airdate: October 8, 2004 |
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| Awakening #084 |
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| 12 Meet Surak (1:37) |
| 13 Archer Remembers Cave / Vulcans On the Attack / Kir'shara (7:03) |
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| Recorded November 17–18, 2004 |
| Original Airdate: November 26, 2004 |
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| Bound #093 |
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| 14 Slave Girl Dance (2:07) |
| 15 Kelby Under the Spell (1:20) |
| 16 Captain Romantic / Disoriented Captain (4:00) |
| 17 Harrad-Sar Attacks / Trip Foils Slave Girls (5:27) |
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| Recorded March 15–16, 2005 |
| Original Airdate: April 15, 2005 |
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| Terra Prime #097 |
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| 18 Five Seconds to Impact (2:02) |
| 19 Her Name Is Elizabeth (1:19) |
| 20 Archer's Speech (1:49) |
| 21 Grieving (2:22) |
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| Recorded April 22, 2005 |
| Original Airdate: May 13, 2005 |
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| BONUS TRACK |
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| The Catwalk #038 |
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| 22 Into the Sunset (0:32) |
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| Recorded December 11, 2002 |
| Original Airdate: December 18, 2002 |
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| 23 Where My Heart Will Take Me (End Credits Instrumental) (0:49) |
| (Diane Warren) |
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| Disc 3 |
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| Veterans and New Recruits |
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| 01 Archer's Theme (Unused Main Title) (1:24) (Dennis McCarthy) |
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| Horizon #046 (Mark McKenzie) |
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| 02 Travis in Sweet Spot / Change of Course (1:37) |
| 03 Up Your Alley (4:18) |
| 04 Star Map (1:16) |
| 05 We're Under Attack (1:50) |
| 06 Band of Brothers (3:33) |
| 07 Never Better Sir (1:23) |
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| Recorded April 2, 2003 |
| Original Airdate: April 16, 2003 |
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| Terra Nova #006 (David Bell) |
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| 08 Phaser Cuts Log (1:48) |
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| Recorded October 16, 2001 |
| Original Airdate: October 24, 2001 |
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| Dear Doctor #013 (David Bell) |
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| 09 Doc's First Installment / Phlox Needs a Friend (3:46) |
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| Recorded October 16, 2001 |
| Original Airdate: October 24, 2001 |
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| The Andorian Incident #007 (Paul Baillargeon) |
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| 10 Sanctuary Interrupted (0:47) |
| 11 Sensor Array (2:32) |
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| Recorded October 23, 2001 |
| Original Airdate: October 31, 2001 |
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| Vox Sola #022 (Paul Baillargeon) |
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| 12 Force Field Ready / Take Me Home / Crew Released / Home of the Tendril (3:28) |
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| Recorded April 17, 2002 |
| Original Airdate: May 1, 2002 |
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| First Flight #050 (Paul Baillargeon) |
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| 13 Prototype Crash (3:34) |
| 14 See You Out There (1:41) |
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| Recorded May 1, 2003 |
| Original Airdate: May 14, 2003 |
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| Proving Ground #065 (John Frizzell) |
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| 15 Recap (1:32) |
| 16 Turning the Tables (4:12) |
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| Recorded January 13, 2004 |
| Original Airdate: January 21, 2004 |
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| Silent Enemy #012 (Velton Ray Bunch) |
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| 17 First Encounter (2:03) |
| 18 Taking Risks / Showdown (4:44) |
| 19 Pineapple Cake (0:59) |
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| Recorded December 11, 2001 |
| Original Airdate: January 16, 2002 |
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| Desert Crossing #024 (Velton Ray Bunch) |
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| 20 Warm Welcome (1:14) |
| 21 Geskana Match / Archer Goes for Goal (2:52) |
| 22 Trip's Menu (1:23) |
| 23 The Rescue (3:00) |
| 24 Not Why We're Here (0:59) |
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| Recorded April 30, 2002 |
| Original Airdate: May 8, 2002 |
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| Similitude #062 (Velton Ray Bunch) |
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| 25 In Memoriam (0:43) |
| 26 Warp Drive Test (3:08) |
| 27 You Owe Me One (3:51) |
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| Recorded November 12, 2003 |
| Original Airdate: November 19, 2003 |
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| The Augments #082 (Velton Ray Bunch) |
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| 28 Recap / Teaser–Enterprise 082 (1:51) |
| 29 Pathogen Bomb (3:27) |
| 30 Goodbye Doc (0:39) |
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| Recorded November 4, 2004 |
| Original Airdate: November 12, 2004 |
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| 31 Archer's Theme (End Credits) (0:39) (Dennis McCarthy) |
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| Disc 3 |
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| Fan Favorites |
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| In a Mirror, Darkly, Parts I and II #094 (Dennis McCarthy & Kevin Kiner) |
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| 01 First Contact Revisited (1:49) |
| (Jerry Goldsmith, Dennis McCarthy & Kevin Kiner) |
| 02 Mirror Main Title From Enterprise (1:21) |
| 03 Mutiny (3:53) |
| 04 Dangerous Seduction (2:43) |
| 05 Counter Attack (2:31) |
| 06 Boarding the Defiant (2:23) |
| 07 Tholian Web (2:08) |
| 08 Abandon Enterprise (1:59) |
| 09 Recap–Enterprise 095 (1:00) |
| 10 Defiant Trapped / Defiant Fights Back (2:49) |
| 11 T'Pol Interrogation (1:31) |
| 12 Booby Trap (2:26) |
| 13 Gorn to Die (2:53) |
| 14 Defiant to the Rescue (2:14) |
| 15 T'Pol Busted (2:05) |
| 16 Phlox Sabotage (1:55) |
| 17 Avenger Attacks (2:02) |
| 18 Empress Hoshi (1:16) |
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| Recorded March 30, 2005 |
| Original Airdates: April 22 and 29, 2005 |
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| Regeneration #049 (Brian Tyler) |
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| 19 Borg Crash Site / Borg Awakening (3:13) |
| 20 Archer Tells Plan / Distress Call / Phlox Attacked (3:10) |
| 21 Hive Mind / Borg Hunt / Dead in the Water (6:43) |
| 22 Borg Attack / Borg Attack 2 (7:23) |
| 23 Message in a Bottle / Postponed (0:58) |
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| Recorded April 22, 2003 |
| Original Airdate: May 7, 2003 |
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| These Are The Voyages #098 (Dennis McCarthy & Kevin Kiner) |
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| 24 Freeze Program / Enterprise D (0:59) |
| 25 Narrow Escape (1:24) |
| 26 Under Attack / Trip Hurt (4:28) |
| 27 Trip's Possessions / It Was Worthwhile (1:46) |
| 28 Heroic / Trek Theme Montage (2:11) |
| (Jerry Goldsmith, Alexander Courage & Gene Roddenberry, Dennis McCarthy & Kevin Kiner) |
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| Recorded April 29, 2005 |
| Original Airdate: May 13, 2005 |
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| 29 Archer's Theme (End Credits) (Dennis McCarthy) / Paramount Studios Logo (0:51) (Lalo Schifrin) |
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