| Disc 1 |
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| 01 Main Title* (2006 recording, cello version) 0:52 |
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| THE ENEMY WITHIN (Total Time: 22:59) |
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| 02 The Rock Slide*/Beam Up*/ The Evil Kirk M11/M12/M13 1:11 |
| 03 Alter Ego* M14 1:01 |
| 04 The Tired Captain* M15 0:42 |
| 05 Brandy M16 0:48 |
| 06 The Lascivious Captain M17–21 2:37 |
| 07 Bruised Knuckles/An Impostor M22/M23 1:34 |
| 08 Kirk's Log*/Indecisive*/Evil Fury M24/M31/M32 2:48 |
| 09 Confrontation* M33 2:18 |
| 10 The Prone Body*/Shivering Sulu*/No Repair M34–41/M42/M43 0:37 |
| 11 What to Do?* M44 0:43 |
| 12 Another Brandy/The Evil Grin/Double Dog Death* M45/M46/M51 1:24 |
| 13 Spock Takes Over*/Help Me* M52/M53 2:04 |
| 14 Evil Triumphs M54–61 1:06 |
| 15 Two Into One* M62 2:18 |
| 16 One Captain Kirk*/Thank You, Yeoman* M63/M64 1:19 |
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| THE CONSCIENCE OF THE KING (Total Time: 26:14) |
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| 17 Dagger Sweet'ner/Go for Baroque/Play-Off #1 M11A/M11/M12 1:26 |
| 18 Spaceship Titles*/Dr. Leighton's Face/Bridge #1* M13/M14/M15 1:12 |
| 19 Quasi-Sex* (Theme From STAR TREK, jazz version; Courage/Roddenberry, arr. Mullendore) LM5 1:37 |
| 20 Lenore M16–21 1:45 |
| 21 Kirk and Lenore*/He's Dead M22/M23 1:43 |
| 22 Spaceship*/5 Sex and a ½/Play-Off #2* M24/M25/M26 1:10 |
| 23 Spaceship Play-On*/Toast and Corridor*/Lenore's Kiss/Short Bridge M27/M31/M32/M33 2:31 |
| 24 Poison M41 0:37 |
| 25 Play-On #2*/Quick Ship*/Phaser Overload M42/M43/M44 1:39 |
| 26 Kodos?/Voice Test M45/M46 1:33 |
| 27 Everything Is Later*/Play-Off #3* M51/M52 1:52 |
| 28 Ship Play-On*/Woodwind Fanfare/Riley Gone M53/M54/M55 1:10 |
| 29 Go for Baroque M11 (M56) 1:25 |
| 30 I Know That Voice/All Ghosts Dead M57/M58–61 3:02 |
| 31 Opheliamania*/Bridge #2*/Last Cue* M62/M63/M64 3:02 |
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| SHORE LEAVE (Total Time: 20:35) |
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| 32 New Planet/Rabbit Music M10A/10B 2:21 |
| 33 School Chum/Finnegan M23/M23A 1:40 |
| 34 2nd Ruth (Ruth) M31A 2:38 |
| 35 Old English/Tiger/Costume/Birds/SamuraiM33/M33A/M33B/M34/M34A 3:51 |
| 36 Knight/Joust M41/M41A 1:28 |
| 37 Dummy/Like Real M43/M44 0:57 |
| 38 A Clue/Finnegan's Return/The Leg Trick/Dirt Trick M45–50 Pt. 1/M45–50 Pt. 2/M51/M53 4:34 |
| 39 Tiger Thoughts/Strafing/2nd Samurai/Caretaker/Lazarus M55–60/M55–60A/M55–60B/M61/M62 2:03 |
| 40 2nd Ruth/Ruth to Commercial (2nd Ruth) M31A/M24B 0:51 |
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| FIRST SEASON LIBRARY MUSIC (Total Time: 7:38) |
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| 41 Impension* LM1 (cond. Steiner) 1:10 |
| 42 Lonely to Dramatic* LM3 (cond. Steiner) 1:27 |
| 43 Romantic Scene* LM6 (cond. Steiner) 0:47 |
| 44 Love Scene* LM4 (cond. Steiner) 1:16 |
| 45 Pensive Mood* 13LM2 (cond. Mullendore) 2:10 |
| 46 Play-Off (with button)* 13LM5 (cond. Mullendore) 0:15 |
| 47 Play-Off (with sustain)* 13LM5A (cond. Mullendore) 0:19 |
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| * Contains "Theme From STAR TREK (TV Series)" by Alexander Courage and Gene Roddenberry |
| Tracks 41–44 recorded with "The Corbomite Maneuver," "Balance of Terror" and "What Are Little Girls Made Of?" (Vol. 1). |
| Tracks 45–47 recorded with "The Conscience of the King" (pg. 7). |
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| Disc 2 |
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| 01 Main Title* (2nd Season, Soprano Version) 1:01 |
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| CATSPAW (Total Time: 31:30) |
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| 02 Starship*/Captain Kirk M11/M12+M12X 1:13 |
| 03 Orbiting Ship*/Fog Planet M13/M13A+M13B 1:51 |
| 04 Thicker Fog/Witches M14+M14A/M15 1:48 |
| 05 Fog Storm/Castle/Second Castle M16–20+M16–20A/M21/M22 2:28 |
| 06 Cat Music/Enterprise* M22X/M22A 1:05 |
| 07 Follow That Cat/Brain-Washed M23/M24 2:10 |
| 08 Drugged/Scene Change Sweetener/Korob/Lap Kitten/Cat as Hostess/Free Meal/The Bribe M25/M25A/M26/M31/M32/M33+M33A/M34 3:27 |
| 09 Sylvia/Unguarded Entrances/Sympathetic Magic M35/M36/M37+M37X 2:42 |
| 10 Cooking Lesson/Force Field M41/M42 1:31 |
| 11 Defeated Captain/Music to Dent Force Fields By M43/M44 1:06 |
| 12 Bones, the Zombie M45 0:45 |
| 13 Love, Sort Of M51 3:26 |
| 14 Kirk Caught/Rescue M52/M53 0:52 |
| 15 Racial Memories/Captain Kirk/Mace Fight M54–60/M54–60A/M61 3:32 |
| 16 Giant Cat M62+M25A 1:32 |
| 17 Wand-Breaking/The Prototypes/Five to Beam Up* M63+M25A/M64+64B/M64A 1:33 |
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| FRIDAY'S CHILD (Total Time: 23:23) |
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| 18 Ship*/Capella IV M11/M12 1:09 |
| 19 Captain's Log* M13A/M13 2:06 |
| 20 Klingon Ship/Music for Fruits/The Teer M14/M15/M16-20 1:26 |
| 21 The Challenge/Klingon Blip M21/M21A 1:09 |
| 22 Distress Signal M22 1:43 |
| 23 Arm Barbeque/Slow Turn/Call of Duty M24/M25/M26 0:56 |
| 24 Scott/Bones' Good Idea/Capellan Desert M31/M32/M33A 2:16 |
| 25 Belly Feeler M34 2:13 |
| 26 Sonic Ambush/Bouncing Boulder M35/M36 1:03 |
| 27 Kras on the Rocks/Paternity Case/New Capellan in Town M41/M45/M51 1:43 |
| 28 Negative Report/Old Russian Saying/The Mother Splits M53/M54/M55 1:34 |
| 29 The Baby Sitter/Road Hog M56/M57 0:44 |
| 30 Down the Throat M58 1:13 |
| 31 Arrows M61 1:29 |
| 32 Forfeit M62 1:32 |
| 33 Coochy Coo*/Godfathers* M63/M64 0:40 |
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| FIRST SEASON LIBRARY MUSIC (Total Time: 17:11) |
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| 34 Love Scene* 13LHM3 (cond. Mullendore) 1:29 |
| 35 Humoresque* 13LHM7 (cond. Mullendore) 0:43 |
| 36 Humoresque (tag)* 13LHM7A (cond. Mullendore) 0:13 |
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| From "Charlie X" (cond. Steiner) |
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| 37 That's a Girl M12X 0:42 |
| 38 Kirk's Command M13X 0:57 |
| 39 Charlie's Mystery M14X 0:45 |
| 40 Kirk Puzzled (Library Version #1) M34X 0:39 |
| 41 Kirk Puzzled (Library Version #2) M34Y 0:22 |
| 42 Kirk Puzzled (Library Version #3) M34Z 0:15 |
| 43 Zap Sam M41X 1:01 |
| 44 Zap the Pistol (Library Version #1) M42X s1 0:42 |
| 45 Zap the Pistol (Library Version #2) M42X s2 0:12 |
| 46 Standoff (Library Version #1) M43X 0:54 |
| 47 Standoff (Library Version #2) M43Y 0:17 |
| 48 Standoff (Library Version #3) M43Z 0:09 |
| 49 Zap Janice M52X 1:00 |
| 50 Zap the Spaceship (Library Version #1) M54X s1 0:09 |
| 51 Zap the Spaceship (Library Version #2) M54X s2 0:06 |
| 52 Charlie's Friend (Library Version #1) M61X s1 0:41 |
| 53 Charlie's Friend (Library Version #2) M61X s3 0:10 |
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| From "Mudd's Women" (cond. Steiner) |
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| 54 The Last Crystal (Library Version #1) M31X 0:14 |
| 55 The Last Crystal (Library Version #2) M31X s3 0:08 |
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| From "The Corbomite Maneuver" (cond. Steiner) |
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| 56 Condition Alert M13A 0:14 |
| 57 Hideous Balok M33A 0:25 |
| 58 Baby Balok M61 0:31 |
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| From "Balance of Terror" (cond. Steiner) |
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| 59 Theme From STAR TREK* (Library Version #1) 9MA pt 1 0:13 |
| 60 Theme From STAR TREK* (Library Version #1) 9MA pt 2 0:15 |
| 61 Theme From STAR TREK* (Library Version #1) 9MA pt 3 0:12 |
| 62 Theme From STAR TREK* (Library Version #1) 9MA pt 4 0:12 |
| 63 Romulan Theme M22/M22A s1 0:52 |
| 64 Edith Must Die (Library) M47B ("City on the Edge of Forever," Steiner) 0:12 |
| 65 Joe Berserk (alternate) M21 s3 ("The Naked Time," Courage) 0:14 |
| 66 Leg Trick (alternate) M51/M51A ("Shore Leave," Fried) 1:02 |
| 67 End Title* (2nd Season, Soprano Version) 0:47 |
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| * Contains "Theme From STAR TREK (TV Series)" by Alexander Courage and Gene Roddenberry |
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