| Disc 1 |
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| Music by Dennis McCarthy |
| * Music by Dennis McCarthy & Kevin Kiner |
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| 01 Where My Heart Will Take Me |
| (Main Title, Season Three) (1:21) |
| Written by Diane Warren |
| Performed by Russell Watson |
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| Breaking the Ice #008 |
| 02 Archer's Comet/Comet Chasers (2:03) |
| 03 The Comet (2:18) |
| Recorded October 30, 2001 |
| Original Airdate: November 7, 2001 |
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| Sleeping Dogs #015 |
| 04 Dive (1:49) |
| Original Airdate: January 30, 2002 |
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| The Communicator #034 |
| 05 Searching/It's Not There (3:59) |
| 06 Great Escape (2:52) |
| Recorded November 5, 2002 |
| Original Airdate: November 13, 2002 |
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| Stigma #040 |
| 07 A Promise/Yuris Saves the Day (3:11) |
| Recorded February 5, 2003 |
| Original Airdate: October 8, 2003 |
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| Future Tense #042 |
| 08 Attacked (3:26) |
| 09 Final Attack (3:10) |
| Recorded November 11, 2003 |
| Original Airdate: February 19, 2003 |
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| Cogenitor #048 |
| 10 Visitor (2:31) |
| 11 Responsibility (4:16) |
| Recorded April 15, 2003 |
| Original Airdate: April 30, 2003 |
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| The Xindi #053 |
| 12 Recap/Xindi Meeting (2:34) |
| 13 Escape (3:39) |
| Recorded September 2, 2003 |
| Original Airdate: September 10, 2003 |
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| Doctor's Orders* #068 |
| 14 Empty Ship (1:28) |
| 15 Phlox to the Rescue (3:16) |
| Recorded February 9, 2004 |
| Original Airdate: February 18, 2004 |
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| Damage* #071 |
| 16 Bad Dream (3:40) |
| 17 Hijackers/No Choice (5:36) |
| Recorded March 17, 2004 |
| Original Airdate: April 21, 2004 |
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| Observer Effect* #087 |
| 18 Your Move (1:45) |
| 19 One Way Nap (3:13) |
| 20 Hoshi Dies (4:18) |
| 21 Archer Out of Options (2:31) |
| 22 More Than Observe/Rules Need to Change (1:06) |
| Recorded February 16 & 22, 2004 |
| Original Airdate: January 21, 2005 |
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| The Aenar* #090 |
| 23 Recap - Enterprise 090/Hunt Down Enterprise (2:18) |
| 24 Telepresence Test Fails (2:31) |
| 25 Freighter Fight (2:15) |
| 26 Telepathic Siblings/ Trip Hits the Road (3:10) |
| Recorded February 2, 2005 |
| Original Airdate: February 11, 2005 |
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| Disc 2 |
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| Music by Jay Chattaway |
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| 01 Archer's Theme |
| (Bumper Version #1) (0:07) |
| (Dennis McCarthy) |
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| Fight or Flight #003 |
| 02 Archer Reverses Course (1:20) |
| 03 Aliens Return/Damn the Torpedoes/Failure to Communicate/Hoshi Gets Through (10:08) |
| Recorded September 25, 2001 |
| Original Airdate: October 3, 2001 |
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| Detained #021 |
| 04 Danik to Isolation (2:23) |
| 05 Big Bang/Suliban Liberation (3:46) |
| Recorded April 5, 2002 |
| Original Airdate: April 24, 2002 |
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| Carbon Creek #027 |
| 06 Welcome to Carbon Creek/Wearing It Backwards (1:31) |
| 07 The Hustler (1:55) |
| 08 Get a Job/Mestral's Secret Date (1:39) |
| 09 Glaring Vulcan (2:03) |
| 10 Vulcan Velcro/Not Enough (3:32) |
| Recorded September 17, 2002 |
| Original Airdate: September 25, 2002 |
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| Anomaly #054 |
| 11 The Sphere (1:20) |
| Recorded September 9, 2003 |
| Original Airdate: September 17, 2003 |
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| E2 #073 |
| 12 Recap/Future T'Pol (1:11) |
| 13 Enterprise 2/117 Years Early (3:24) |
| 14 Father Son Talk 2/Reunion (2:29) |
| 15 Lorian's Plan/Standoff (4:28) |
| 16 Joining Forces/Team Enterprise/ |
| Subspace Passage/Remembrance (6:26) |
| Recorded April 14, 2004 |
| Original Airdate: May 5, 2004 |
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| Cold Station 12 #081 |
| 17 Lucas Cracks/Stasis Chamber/Soong Escapes (7:40) |
| Recorded October 27, 2004 |
| Original Airdate: November 5, 2004 |
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| Divergence #092 |
| 18 Recap - Enterprise 092 (1:03) |
| 19 Prepare for Transfer/Trip Transfer (4:15) |
| 20 Warp Drive Reboot (3:31) |
| 21 Krell Demands Surrender (3:00) |
| 22 Krell Attacks/Klingons Disabled/Phlox Fools Krell (6:20) |
| 23 Thanks for the Help/One Captain (0:44) |
| Recorded February 25, 2005 |
| Original Airdate: February 25, 2005 |
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| Disc 3 |
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| Veterans |
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| 01 Where My Heart Will Take Me |
| (Bumper #1) (0:07) |
| (Diane Warren) |
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| Fusion #017 (David Bell) |
| 02 T'Pol Tells Dream (1:58) |
| 03 First Dance I Went To (1:50) |
| Recorded February 19, 2002 |
| Original Airdate: February 27, 2002 |
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| Dawn #039 (David Bell) |
| 04 Trip Crash Lands (1;33) |
| 05 Trip Tosses Phaser/The Big Fight (4:31) |
| 06 Trip Reviews Life (2:09) |
| 07 Leave This System/Glad I Missed (1:22) |
| Recorded December 20, 2002 |
| Original Airdate: January 8, 2003 |
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| The Crossing #044 |
| (Paul Baillargeon) |
| 08 Enterprise Swallowed (1:04) |
| 09 Wisps First Contact (4:06) |
| 10 Wisps Take Trip (2:50) |
| 11 Wisps Chase Reed/Alien Reed/More Crew Taken (6:39) |
| 12 They're Lying to Us (1:15) |
| 13 Alien Trip Listens In/ |
| Phlox Pulls Panel/Trip Fights Phlox/End of Wisps (7:24) |
| Recorded March 18, 2003 |
| Original Airdate: April 2, 2003 |
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| Rajiin #056 (Paul Baillargeon) |
| 14 Intimate Intruder/Rajiin Captured (5:09) |
| Recorded September 24, 2003 |
| Original Airdate: October 1, 2003 |
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| Chosen Realm #064 |
| (Paul Baillargeon) |
| 15 Crew Fights Back/Hand to Hand/Final Fight (8:18) |
| Recorded December 16, 2003 |
| Original Airdate: January 14, 2004 |
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| Hatchery #069 (Paul Baillargeon) |
| 16 Recap/Crashed Ship (1:31) |
| 17 Endangered Mission (2:37) |
| 18 Hatching Time (1:37) |
| 19 Mutiny/Return to Duty (6:40) |
| Recorded February 18, 2004 |
| Original Airdate: February 25, 2004 |
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| The Forgotten #072 |
| (Paul Baillargeon) |
| 20 Recap/For the 18 (2:16) |
| 21 Emotions (1:51) |
| 22 Trip Dreams (1:21) |
| 23 Reptilian Attack (3:06) |
| 24 Goodbye Elizabeth (2:27) |
| Recorded March 3, 2004 |
| Original Airdate: April 28, 2004 |
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| Disc 4 |
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| New Recruits |
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| 01 Where My Heart Will Take Me |
| (Bumper #2) (0:12) (Diane Warren) |
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| Canamar #043 (Brian Tyler) |
| 02 Shuttlepod Adrift/Start the Investigation/Kuroda Gets Free (2:37) |
| 03 Pilot Knocked Out/Crew Gets Message (2:15) |
| 04 Kuroda's Plan (1:25) |
| 05 Piece of Cake (3:34) |
| 06 End of Kuroda (6:17) |
| Recorded February 18, 2003 |
| Original Airdates: February 26, 2003 |
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| The Forge #083 (John Frizzell) |
| 07 Vulcan Catacombs (1:17) |
| 08 Rogue Bomb (2:09) |
| 09 Sandfire/Mindmeld (4:25) |
| 10 Syrranite Sanctuary (2:25) |
| Recorded November 11, 2004 |
| Original Airdate: November 19, 2004 |
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| Acquisition #019 |
| (Velton Ray Bunch) |
| 11 Krem & Muk on Board (3:40) |
| 12 Trip Chased (1:43) |
| 13 Ferengi Showdown/Seductive Vulcan (5:03) |
| 14 Vault Scheme/Krem Gets His Ship (4:41) |
| Recorded March 19, 2002 |
| Original Airdate: March 27, 2002 |
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| Exile #058 (Velton Ray Bunch) |
| 15 The Voice Returns/Alien Garden/Meet Tarquin (4:59) |
| 16 Space Landing (2:56) |
| 17 Last Visit (1:01) |
| Original Airdate: October 15, 2003 |
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| The Council #074 |
| (Velton Ray Bunch) |
| 18 Into the Chamber (4:11) |
| 19 Armaturi Attack (1:39) |
| 20 Reprieve (1:34) |
| 21 End of Degra/News of Degra (1:58) |
| 22 Weapon Launched (2:31) |
| Recorded April 21, 2004 |
| Original Airdate: May 12, 2004 |
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| Affliction #091 |
| (Velton Ray Bunch) |
| 23 Bad Medicine (1:00) |
| 24 Mind Meld Memory (2:39) |
| 25 T'Pol's Daydream (2:25) |
| 26 Klingon Augments (2:47) |
| 27 Columbia First Flight (2:01) |
| 28 Warp 5.2 (2:51) |
| Recorded February 10, 2005 |
| Original Airdate: February 18, 2005 |
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| 29 Archer's Theme (End Credits) |
| (Dennis McCarthy) /Paramount Studios Logo (0:51) |
| (Lalo Schifrin) |
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